Translations:System Settings/Startup and Shutdown/8/en

From KDE UserBase Wiki

Clicking Add Program... opens the usual application picker dialog from which you can select an application. A desktop file for the application will be created in the autostart folder. When you have selected an application a Properties dialog will open. Just click OK and you are done. You can modify the properties of the application later: select the application in the list and click Properties to bring up the dialog again.